708-27 medium duty-clear cement

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  1. Identification

Product identifier :  PVC Medium Cement

  1. Hazard(s) identification

Physical hazards Health hazards

 

Environmental hazards Label elements

Flammable liquids

Physical hazards not otherwise classified Acute toxicity, oral

Skin corrosion/irritation

Serious eye damage/eye irritation

Specific target organ toxicity, single exposure Specific target organ toxicity, single exposure Aspiration hazard

Health hazards not otherwise classified Not classified.

Category 2

Category 1

Category 4

Category 2 Category 2A

Category 3 respiratory tract irritation Category 3 narcotic effects Category 1

Category 1

 

Signal word                                  Danger

Hazard statement                      Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary statement

Prevention                           Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use non-sparking tools. Take action to prevent static discharges. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

 

Response                             IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting. Take off contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish.

Storage                                 Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal                               Dispose of contents/container in accordance with local/regional/national/international regulations.

Other hazards                                     Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

May form explosive peroxides.

Supplemental information               Not applicable.

 

3. Composition/information on ingredients

Mixtures Chemical name

 

 

 

CAS number

 

 

 

%

Furan, Tetrahydro- 109-99-9 30-60
Acetone 67-64-1 10-26
Methyl ethyl ketone 78-93-3 10-26
Ethene, chloro-, homopolymer, Polyvinyl chloride; PVC; 9002-86-2 12-20
Cyclohexanone 108-94-1 10-20
Fumed Silica 112946-62-6 1-6

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

  1. First-aid measures

Inhalation Skin contact

 

Eye contact Ingestion

 

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

 

General information

 

  1. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Immediately flush eyes with plenty of water for at least 16 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. If ingestion of a large amount does occur, call a poison control center immediately.

Causes eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea.

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.

 

Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.

 

Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

 

Fire fighting equipment/instructions

Specific methods

 

General fire hazards

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.

Use standard firefighting procedures and consider the hazards of other involved materials. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out.

Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age.

 

  1. Accidental release measures

 

Personal precautions, protective equipment and emergency procedures

 

Methods and materials for containment and cleaning up

 

Environmental precautions

  1. Handling and storage

Precautions for safe handling

 

Conditions for safe storage, including any incompatibilities

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.

 

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. This product is miscible in water.

Avoid discharge into drains, water courses or onto the ground.

 

Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling.

Store locked up. Do not handle or store near an open flame, heat or other sources of ignition. Keep away from heat, sparks and open flame. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a closed container away from incompatible materials. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Keep container tightly closed. Store in a well-ventilated place. Keep out of the reach of children. Keep in an area equipped with sprinklers. Use care in handling/storage. Store away from incompatible materials (see Section 10 of the SDS).

 

Flammability limit – upper (%)

11.8

 

Explosive limit – lower (%)       Not available.

Explosive limit – upper (%)       Not available.

Vapor pressure                                  146 mm Hg @ 20 C

Vapor density                                      2.6

Relative density                                 0.93 +/- 0.02

Solubility(ies)

Solubility (water)                        Negligible

 

Partition coefficient (n-octanol/water)

Auto-ignition temperature Decomposition temperature Viscosity

Viscosity temperature Other information

Bulk density

VOC (Weight %)

  1. Stability and reactivity

Reactivity Chemical stability

Possibility of hazardous reactions

Conditions to avoid

 

Incompatible materials

Hazardous decomposition products

Not available.

 

Not available.

Not available.

1200 – 2600 cP

77 °F (26 °C)

 

7.7 lbs/gal

< 610 g/l SCAQMD 1168/M316A

 

The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions.

No dangerous reaction known under conditions of normal use.

 

Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. No hazardous decomposition products are known.

 

  1. Toxicological information

Information on likely routes of exposure

Inhalation                                      May be fatal if swallowed and enters airways. May cause irritation to the respiratory system.

Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful.

Skin contact                                Causes skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Eye contact                                  Causes serious eye irritation.

Ingestion                                       May be fatal if swallowed and enters airways. Harmful if swallowed.

 

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Causes eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

 

Information on toxicological effects

Acute toxicity                                      May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.

 

Components                                           Species

Cyclohexanone (CAS 108-94-1)

Acute

Dermal

LD60                                         Rabbit

Inhalation

LC60                                         Rat

Test Results

948 mg/kg

8000 ppm, 4 hours

Components                                           Species

Oral

LD60                                         Rat

Test Results 

800 mg/kg

 

* Estimates for product may be based on additional component data not shown.

 

Skin corrosion/irritation

Serious eye damage/eye irritation

Respiratory or skin sensitization

Causes skin irritation. Causes serious eye irritation.

 

Respiratory sensitization         Not available.

 

Skin sensitization Germ cell mutagenicity

This product is not expected to cause skin sensitization.

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

 

Carcinogenicity                                  Not classified.

ACGIH Carcinogens

Acetone (CAS 67-64-1)                                                              A4 Not classifiable as a human carcinogen.

Cyclohexanone (CAS 108-94-1)                                              A3 Confirmed animal carcinogen with unknown relevance to humans.

 

Ethene, chloro-, homopolymer, Polyvinyl chloride; PVC; (CAS 9002-86-2)

A4 Not classifiable as a human carcinogen.

 

Furan, Tetrahydro- (CAS 109-99-9)                                         A3 Confirmed animal carcinogen with unknown relevance to

humans.

Canada – Manitoba OELs: carcinogenicity

ACETONE (CAS 67-64-1)                                                         Not classifiable as a human carcinogen.

CYCLOHEXANONE (CAS 108-94-1)                                      Confirmed animal carcinogen with unknown relevance to humans.

 

POLYVINYL CHLORIDE (PVC), RESPIRABLE FRACTION (CAS 9002-86-2)

Not classifiable as a human carcinogen.

 

TETRAHYDROFURAN (CAS 109-99-9)                                  Confirmed animal carcinogen with unknown relevance to humans.

IARC Monographs. Overall Evaluation of Carcinogenicity

Cyclohexanone (CAS 108-94-1)                                              3 Not classifiable as to carcinogenicity to humans.

 

Ethene, chloro-, homopolymer, Polyvinyl chloride; PVC; (CAS 9002-86-2)

3 Not classifiable as to carcinogenicity to humans.

 

Fumed Silica (CAS 112946-62-6)                                           3 Not classifiable as to carcinogenicity to humans.

 

Reproductive toxicity

Specific target organ toxicity – single exposure

Specific target organ toxicity – repeated exposure

This product is not expected to cause reproductive or developmental effects. Narcotic effects. Respiratory tract irritation.

 

Not classified.

 

Aspiration hazard                               May be fatal if swallowed and enters airways.

Chronic effects                                   Prolonged inhalation may be harmful.

 

  1. Ecological information

 

Ecotoxicity

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

 

Components

Cyclohexanone (CAS 108-94-1)

Aquatic

Species

Test Results

 

Fish

LC60

Fathead minnow (Pimephales promelas)

481 – 678 mg/l, 96 hours

 

* Estimates for product may be based on additional component data not shown.

 

Persistence and degradability Bioaccumulative potential

No data is available on the degradability of this product. No data available.

 

Partition coefficient n-octanol / water (log Kow)

Acetone (CAS 67-64-1)                                                              -0.24

Cyclohexanone (CAS 108-94-1)                                             0.81

Furan, Tetrahydro- (CAS 109-99-9)                                        0.46

Methyl ethyl ketone (CAS 78-93-3)                                         0.29

 

Mobility in soil                                      No data available.

Other adverse effects                      No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

  1. Disposal considerations

 

Disposal instructions

Local disposal regulations Hazardous waste code

 

Waste from residues / unused products

 

Contaminated packaging

 

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

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