709-27 heavy duty-clear cement

Telecharger fiche technique

 

PVC HEAVY  DUTY CLEAR

1.  Identification 

Product identifier PVC Heavy Duty Clear or Gray Cement Other means of identification

SDSnumber                                 1102E

Synonyms                                    Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951,31952,

31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050,

32051, 32052, 32210, 32211

Recommendeduse                            Joining PVC Pipes

Recommendedrestrictions             None known.

 

2.  Hazard(s) identification

 

Physical hazards Healthhazards

OSHA defined hazards Labelelements

Flammable liquids

Acute toxicity, oral Skincorrosion/irritation

Serious eye damage/eye irritation

Specific target organ toxicity, single exposureSpecific target organ toxicity, single exposureAspiration hazard

Not classified.

Category2

Category4

Category 2 Category 2A

Category 3 respiratory tract irritation Category 3 narcotic effects Category 1

 

Signalword                                   Danger

Hazardstatement                       Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness ordizziness.

Precautionary statement

Prevention                           Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Use only outdoors or in a well-ventilated area. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/faceprotection.

Response                             Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media toextinguish.

Storage                                 Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store lockedup.

Disposal                               Dispose of contents/container in accordance with local/regional/national/internationalregulations.

 

Hazard(s) not otherwise classified (HNOC)

Supplemental information

Not applicable.

Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen.

3.  Composition/information on ingredients

Mixtures

Chemical name CAS number %
Furan, Tetrahydro- 109-99-9 30-60
2-Propanone 67-64-1 10-30
Cyclohexanone 108-94-1 10-30
Polyvinyl chloride 9002-86-2 10-30
Methyl ethyl ketone 78-93-3 5-10
Colloidal silicon dioxide 112945-52-5 1-5

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4.  First-aid measures

Inhalation                                              Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feelunwell.

Skincontact                                         Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Eyecontact                                           Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medicaladvice/attention.

Ingestion                                               Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs. Aspiration may cause pulmonary edema andpneumonitis.

 

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause redness and pain.

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

 

Generalinformation                           Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing beforereuse.

5.  Fire-fighting measures

Suitableextinguishing media           Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).

 

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Fire fighting equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.

 

Specificmethods                                Use standard firefighting procedures and consider the hazards of other involved materials.

Generalfire hazards                          Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or withage.

 

6.  Accidental release measures

 

Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material.

 

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.

 

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

 

 

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmentalprecautions              Avoid discharge into drains, water courses or onto the ground.

 

7.  Handling and storage

Precautions forsafe handling         Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly afterhandling.

 

Conditions for safe storage, including any incompatibilities

Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers.

 

8.  Exposure controls/personal protection

Occupational exposure limits

U.S. – OSHA

 

 

Components

Type

Value

Form

 

Colloidal silicon dioxide (CAS 112945-52-5)

TWA                                                          0.8 mg/m3                Unspecified.

 

20mppcf                    Unspecified.

 

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

 

Components Type Value
Polyvinyl chloride (CAS 9002-86-2) STEL 5 ppm
TWA 1 ppm
  1. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

 

Components

Type

Value

Form

 

2-Propanone (CAS 67-64-1)

Cyclohexanone (CAS 108-94-1)

Furan, Tetrahydro- (CAS 109-99-9)

PEL                                                           2400 mg/m3

1000 ppm

PEL                                                           200 mg/m3

50 ppm

PEL                                                           590 mg/m3

200 ppm

 

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

 

Components Type Value Form
Methyl ethyl ketone (CAS 78-93-3) PEL 590 mg/m3
200 ppm
Polyvinyl chloride (CAS 9002-86-2) PEL 5 mg/m3 Respirable fraction.
15 mg/m3 Total dust.
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value
Colloidal silicon dioxide (CAS 112945-52-5) TWA 0.8 mg/m3
20 mppcf
US. ACGIH Threshold Limit Values
Components Type Value Form
2-Propanone (CAS 67-64-1) STEL 750 ppm
TWA 500 ppm
Cyclohexanone (CAS 108-94-1) STEL 50 ppm
TWA 20 ppm
Furan, Tetrahydro- (CAS 109-99-9) STEL 100 ppm
TWA 50 ppm
Methyl ethyl ketone (CAS 78-93-3) STEL 300 ppm
TWA 200 ppm
Polyvinyl chloride (CAS 9002-86-2) TWA 1 mg/m3 Respirable fraction.
U.S. – NIOSH
Components Type Value Form
Colloidal silicon dioxide (CAS 112945-52-5) REL 6 mg/m3 Unspecified.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
2-Propanone (CAS 67-64-1) TWA 590 mg/m3
250 ppm
Colloidal silicon dioxide (CAS 112945-52-5) TWA 6 mg/m3
Cyclohexanone (CAS 108-94-1) TWA 100 mg/m3
25 ppm
Furan, Tetrahydro- (CAS 109-99-9) STEL 735 mg/m3
250 ppm
TWA 590 mg/m3
200 ppm
Methyl ethyl ketone (CAS 78-93-3) STEL 885 mg/m3
300 ppm
TWA 590 mg/m3
200 ppm

 

Biological limit values

ACGIH Biological Exposure Indices

 

Components Value Determinant Specimen Sampling Time
2-Propanone (CAS 67-64-1) 50 mg/l Acetone Urine *
Cyclohexanone (CAS 108-94-1) 80 mg/l 1,2-Cyclohexan ediol, with hydrolysis Urine *
8 mg/l Cyclohexanol, with hydrolysis Urine *
Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l Tetrahydrofura n Urine *
Methyl ethyl ketone (CAS 78-93-3) 2 mg/l MEK Urine *

* – For sampling details, please see the source document.

Exposure guidelines

US – California OELs: Skin designation

Cyclohexanone(CAS 108-94-1)                                               Can be absorbed through the skin.

US – Minnesota Haz Subs: Skin designation applies

Cyclohexanone(CAS 108-94-1)                                               Skin designation applies.

US – Tennessee OELs: Skin designation

Cyclohexanone(CAS 108-94-1)                                               Can be absorbed through the skin.

US ACGIH Threshold Limit Values: Skin designation

Cyclohexanone(CAS 108-94-1)                                               Can be absorbed through the skin.

Furan, Tetrahydro-(CAS 109-99-9)                                          Can be absorbed through the skin.

US. NIOSH: Pocket Guide to Chemical Hazards

Cyclohexanone(CAS 108-94-1)                                               Can be absorbed through the skin.

 

Appropriate engineering controls

Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

 

Individual protection measures, such as personal protective equipment

Eye/faceprotection                    Wear safety glasses with side shields (or goggles).

Skin protection

Handprotection                   Wear appropriate chemical resistant gloves.

Other                                     Wear appropriate chemical resistantclothing.

Respiratoryprotection              If engineering controls do not maintain airborne concentrations below recommendedexposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must beworn.

Thermalhazards                         Wear appropriate thermal protective clothing, when necessary.

 

General hygiene considerations

When using, do not eat, drink or smoke. Wash hands after handling and before eating.

 

9.  Physical and chemical properties

Appearance                                         Opaque.or Translucent.

Physicalstate                              Liquid.

Form                                              Liquid.

Color                                              Gray or Clear.

Odor                                                       Solvent.

Odorthreshold                                    Not available.

pH                                                          Notavailable.

Meltingpoint/freezing point              Not available.

 

Initial boiling point and boiling range

151 °F (66.11 °C)

 

Flashpoint                                            14.0 – 23.0 °F (-10.0 – -5.0 °C)

Evaporation rate                                5.5 – 8

 

Flammability(solid, gas)                   Not available.

Upper/lower flammability or explosive limits

 

Flammability limit – lower (%)

Flammability limit- upper(%)

Not available. Not available.

 

Explosive limit -lower (%)        Not available.

Explosive limit -upper (%)        Not available.

Vaporpressure                                   145 mm Hg @ 20 C

Vapordensity                                       2.5

Relativedensity                                  0.88 – 0.92

Solubility(ies)

Solubility(water)                         Negligible

 

Partition coefficient (n-octanol/water)

Auto-ignition temperature Decomposition temperature Viscosity

Other information Bulk density VOC (Weight %)

  1. Stability andreactivity

Reactivity Chemical stability

Possibility of hazardous reactions

Conditions to avoid

 

Incompatible materials

Hazardous decomposition products

Notavailable.

 

Notavailable.

Notavailable.

1200 – 2500 cP

 

7.5 lb/gal

<510 g/l SQACMD 1168/M316A

 

 

The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions.

No dangerous reaction known under conditions of normal use.

 

Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. No hazardous decomposition products are known.

 

11.  Toxicological information

Information on likely routes of exposure

Inhalation                                      May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause irritation to the respiratory system.

Skincontact                                 Causes skin irritation.

Eyecontact                                   Causes serious eye irritation.

Ingestion                                       May be fatal if swallowed and enters airways. Harmful ifswallowed.

 

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

 

Information on toxicological effects

Acutetoxicity                                       May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.

 

Components                                           Species

Cyclohexanone (CAS 108-94-1)

Acute

Dermal

LD50                                         Rabbit

Inhalation

LC50                                         Rat

Test Results

948 mg/kg

8000 ppm, 4 hours

Components                                           Species

Oral

LD50                                         Rat

Test Results

1540 mg/kg

* Estimates for product may be based on additional component data not shown.

Skincorrosion/irritation                    Causes skin irritation.

Serious eye damage/eye irritation

Respiratory or skin sensitization

Causes serious eye irritation.

 

Respiratorysensitization          Not available.

Skinsensitization                        This product is not expected to cause skin sensitization.

Germcell mutagenicity                     No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity                                  Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential inhumans.

Therefore, the IRIS review concludes that these data in aggregate indicate that there is “suggestive evidence of carcinogenic potential” following exposure to THF by all routes of exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. § 1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations of residual vinyl chloride calculated to be contained in this product are well below the threshold for classification in accordance with 29 C.F.R. § 1910.1200.

IARC Monographs. Overall Evaluation of Carcinogenicity

Colloidal silicon dioxide(CAS 112945-52-5)                         3 Not classifiable as to carcinogenicity to humans. Cyclohexanone(CAS 108-94-1)                                               3 Not classifiable as to carcinogenicity to humans.

Polyvinyl chloride(CAS 9002-86-2)                                         3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Polyvinyl chloride(CAS 9002-86-2)                                         Cancer

Reproductivetoxicity                         This product is not expected to cause reproductive or developmental effects.

 

Specific target organ toxicity – single exposure

Specific target organ toxicity – repeated exposure

Respiratory tract irritation. Narcotic effects. Not classified.

 

Aspirationhazard                                May be fatal if swallowed and enters airways.

Chroniceffects                                    Prolonged inhalation may be harmful.

 

12.  Ecological information

Ecotoxicity                                           The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.

 

Components

Cyclohexanone (CAS 108-94-1)

Aquatic

Species

Test Results

Fish

LC50

Fathead minnow (Pimephales promelas)

481 – 578 mg/l, 96 hours

 

* Estimates for product may be based on additional component data not shown.

Persistenceand degradability         No data is available on the degradability of this product.

Bioaccumulativepotential                No data available.

Partition coefficient n-octanol / water (log Kow)

2-Propanone(CAS 67-64-1)                                                              -0.24

Cyclohexanone (CAS108-94-1)                                                      0.81

Furan, Tetrahydro-(CAS 109-99-9)                                                 0.46

Methyl ethyl ketone(CAS 78-93-3)                                                  0.29

Mobilityin soil                                       No data available.

 

Otheradverse effects                       No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from thiscomponent.

 

13.  Disposal considerations

Disposalinstructions                         Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Localdisposal regulations               Dispose in accordance with all applicable regulations.

Hazardouswaste code                     The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

 

Waste from residues / unused products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

 

Contaminatedpackaging                  Empty containers should be taken to an approved waste handling site for recycling or disposal.

Since emptied containers may retain product residue, follow label warnings even after container is emptied.

 

 

14. Other information, including date of preparation or lastrevision

HMIS®ratings                                      Health: 2 Flammability:3

Physical hazard: 0

Disclaimer                                           The information in the sheet was written based on the best knowledge and experience currently available.

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